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Cis- and trans effects and the mechanisms of acid and base hydrolysis of axial ligands in cobalt(III) complexes containing macrocyclic (N4) ligands

✍ Scribed by Rillema, D. Paul.; Endicott, John F.; Barber, John R.

Book ID
127203318
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
727 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy