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Cis - and trans-dioxa-tris-[2.1.1]-σ-homobenzenes

✍ Scribed by Horst Prinzbach; Manfred Maas; Hans Fritz; Gabrielle McMullen

Book ID
104212739
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
232 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

The three dioxa-trla-[2.1.1]4-homobeuzeuea ( 5)-( 7) have beau ayuthealsed. Preliminary thermolysla experimenta la the gas-phare (350-4OO'C) allow a qualitative descriptiou of their thermal isomeri~atiou proceseee.

We recently showed, that for the carbocyclic trie-[2.l.l]+y-homobenzeues (l)/(3) (X-CH2) the dls,dis,dl8 -aud dia,cou,cou-[G2*a2to2]-cycloreversiou, reap., to Z,Z,Z-( 2) and E,E,Z-cyclodecatrieuoue (4), reap., la clearly the kiuetically favoured, ther-

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