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cis-6-Methoxycarbonyl-2,10-dioxa-1-phosphabicyclo[4.4.0]decane 1-Oxide

โœ Scribed by Lane, T. M. ;Rodriguez, O. P. ;Sommese, A. G. ;Cremer, S. E. ;Bennett, D. W.


Book ID
114511492
Publisher
International Union of Crystallography
Year
1995
Tongue
English
Weight
301 KB
Volume
51
Category
Article
ISSN
0108-2701

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Synthesis and X-ray study of cis and tra
โœ Irene L. Odinets; Natalya M. Vinogradova; Konstantin A. Lyssenko; Pavel V. Petro ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 200 KB ๐Ÿ‘ 2 views

Intramolecular cyclization of bis(3chloropropyl)-diethoxythiophosphorylacetonitrile 7, taking place under distillation in vacuo, yields 6-cyano-2-oxa-10-thia-1-phosphabicyclo[4.4.0]decane-1oxide 10 as a mixture of cis and trans isomers in a 2.3:1 ratio. The isomers were separated chromatographically