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cis-2,5-Disubstituted tetrahydrofurans from pyranosides: A novel example of remote stereocontrol by the aglycone

โœ Scribed by Huiping Zhang; Phyllis Wilson; Weifang Shan; Zheming Ruan; David R. Mootoo


Book ID
103400940
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
217 KB
Volume
36
Category
Article
ISSN
0040-4039

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Oxidative cyclization of isomeric 5,6\_dihydroxyalkenes of type 1 derived from neryl and geranyl acetates with Cr(V1) 0x0 species afford cis-THF diols of type 2 (syn addition across the double bond) with >99.5% stereospecificity.