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Circular dichroism properties of (3S,5R)-cis- and (3S,5S)-trans-3,5-dimethylvalerolactones

✍ Scribed by F.I. Carroll; Asha Sobti; R. Meck


Book ID
104247381
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
193 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


The relationship between the sign of the Cotton effect of optically active lactones and absolute configuration is a subject of current interest. Klyne has formulated a sector rule


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A catalytic deuteration of protected 3,4-dehydro-L-proline using RuCI2(PPh3) 3 followed by RuO~-oxidation gave a 3,4-dideuterated L-pyroglutamic acid derivative which is considered to be a promising precursor for various deuterated amino acids. The present study demonstrates a stereoselective reduct