Circular dichroism properties of (3S,5R)-cis- and (3S,5S)-trans-3,5-dimethylvalerolactones
β Scribed by F.I. Carroll; Asha Sobti; R. Meck
- Book ID
- 104247381
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 193 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The relationship between the sign of the Cotton effect of optically active lactones and absolute configuration is a subject of current interest. Klyne has formulated a sector rule
π SIMILAR VOLUMES
The synthesis of optically active lactones lla and lib is reported, utilizing chiral aldehyde 1 as the key intermediate.-
A catalytic deuteration of protected 3,4-dehydro-L-proline using RuCI2(PPh3) 3 followed by RuO~-oxidation gave a 3,4-dideuterated L-pyroglutamic acid derivative which is considered to be a promising precursor for various deuterated amino acids. The present study demonstrates a stereoselective reduct