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Circular Dichroism of Planar, Exocyclic S-cis-Butadienes Remotely Perturbed

✍ Scribed by Zou Zhichen; Luis Schwager; Pierre-Alain Carrupt; Pierre Vogel

Book ID
102860067
Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
721 KB
Volume
71
Category
Article
ISSN
0018-019X

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✦ Synopsis

An exocyclic butadiene moiety means that each double bond is in an exocyclic position on the ring skeleton.

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## Abstract The rates of photo‐oxidation of exocyclic __S‐cis__‐butadienes grafted onto bicyclo‐[2.2.1]heptanes and 7‐oxabicyclo[2.2.1]heptanes (**1–6**) are dependent upon remote modifications of the bicyclic skeletons. They correlate with the rates of __Diels‐Alder__ additions of these dienes to