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Circular dichroism of monocyclic and bicyclic lactones. Restricted and rigid model compounds for the ester chromophore

✍ Scribed by Toniolo, Claudio.; Perciaccante, Vincent.; Falcetta, Joseph.; Rupp, Raymond.; Goodman, Murray.

Book ID: 126162439
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 723 KB
Volume: 35
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00826a002

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## Abstract The far‐ultraviolet circular dichroic spectrum of the 39‐residue peptide hormone porcine corticotropin and the biologically active fragment corticotropin 1–24 is negative from 250 nm to 195 nm in water, but in 6__M__ guanidinium chloride a positive band appears at about 225 nm. The temp