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Circular dichroism and molecular conformation of copper(II)–gramicidin S complexes

✍ Scribed by P. De Santis; L. D'Ilario; G. Lamanna; S. Morosletti; M. Savino

Publisher
Wiley (John Wiley & Sons)
Year
1973
Tongue
English
Weight
474 KB
Volume
12
Category
Article
ISSN
0006-3525

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✦ Synopsis

Abstract

Optical properties in different solvents of gramicidin‐bis (salicylaldimine) Cu(II) and (5‐I‐salicyladimine) Cu(II) chelates are intercepted in terms of their molecular structure. A molecular model for the inversion of Contton effects in two different classes of solvents is proposed. This explanation is supported by the study of optical properties of model compounds.

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