## CIDNP-detactcd ESR spectra of short-hvcd radxal pairs in the photolysis of qunone (pbemzoquinon~ end duroquinone) have been sludied The infh~cnce of lhe saluraung rf-tield amplitude on the ESR spect.xa of radical pairs detected by lhis melhod hes been dcmonskucd and invatigatcd
CIDNP Investigation of Radical Decay Pathways in the Sensitized Photolysis of Triphenylsulfonium Salts
β Scribed by Eckert, Gerd; Goez, Martin
- Book ID
- 126930907
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 105 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The thermodynamic criterion or reversible electron phototransfer correlates with CIDNP effects in sensitized trans-cis photoisome~tion ol fumaronitrile in aoetonirrile. It tallows from CIDNP analysis xhat rhc free radical anion OF FIJITIWOII~~~~~C does no1 undergo geometrial isomerization
The acetone-sensitized photolysis of 5-bromouracil (BrU), 1-methyl-5-bromouracil (MeBrU) and 5-bromouridine (BrUd) in deoxygenated aqueous solution in the presence of alcohols was studied on irradiation at 254 nm. BrU is converted to uracil with the release of Br-, as shown by UV analysis and high p