CIDNP detected ESR of short-lived biradicals
β Scribed by E.G. Bagryanskaya; Yu.A. Grishin; R.Z. Sagdeev
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 174 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The influence of pumping the electron resonance transitions in intermediate radical particles on CIDNP effects has been observed for the first time. This phenomenon has been employed to take ESR spectra of short-lived biradicals in the photolysis of cyclododecanone in solution.
π SIMILAR VOLUMES
## CIDNP-detactcd ESR spectra of short-hvcd radxal pairs in the photolysis of qunone (pbemzoquinon~ end duroquinone) have been sludied The infh~cnce of lhe saluraung rf-tield amplitude on the ESR spect.xa of radical pairs detected by lhis melhod hes been dcmonskucd and invatigatcd