✦ LIBER ✦

CIDEP in the photosensitized dissociation of benzylchloride

✍ Scribed by Akio Kawai; Tetsuo Okutsu; Kinichi Obi

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 301 KB
Volume: 198
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85041-8

No coin nor oath required. For personal study only.

✦ Synopsis

Photosensitized reactions of benzylchloride are studied by the time-resolved ESR method. Benzyl radicals with emission/absorption multiplet pattern are generated in acetone and acetophenone sensitized reactions. The energetics of sensitizers and benzylchloride lead us to conclude that benzylchloride dissociates even from low vibronic levels of the lowest triplet state.

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