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Chronopotentiometric Studies of Ferrocene Derivatives. I. Determination of Substituent Constants with Substituted Phenylferrocenes

✍ Scribed by Little, William F.; Reilley, Charles N.; Johnson, J. Donald.; Lynn, Kay N.; Sanders, Ann P.

Book ID
127348570
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
672 KB
Volume
86
Category
Article
ISSN
0002-7863

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## Abstract Thermodynamic p__K__~a~‐values have been determined for 38 4‐substituted quinuclidinium perchlorates. They are remarkably sensitive to the polar effect of the substituent and cover a range of 3.63 p__K__~a~ units. Furthermore, they vary linearly and almost equally with temperature since