𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chromium(v)-oxo and chromium(iii)-superoxo complexes bearing a macrocyclic TMC ligand in hydrogen atom abstraction reactions

✍ Scribed by Cho, Jaeheung; Woo, Jaeyoung; Eun Han, Jung; Kubo, Minoru; Ogura, Takashi; Nam, Wonwoo


Book ID
121445180
Publisher
The Royal Society of Chemistry
Year
2011
Tongue
English
Weight
270 KB
Volume
2
Category
Article
ISSN
2041-6520

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Nucleophilic and electrophilic promotion
✍ David R. Bessire; Robert A. Holwerda 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB 👁 2 views

Base hydrolysis reactions of [Cr(tmpa)(NCSe)] 2 O 2ϩ , [Cr(tmpa)(N 3 )] 2 O 2ϩ , and follow the pseudo-first-4ϩ 2ϩ [Cr (tmpa) (ϪO)(ϪPhPO )] [ Cr (tmpa) (ϪO)(ϪCO )] 2 2 4 2 2 3 order relationship (excess OH Ϫ ): For the com- obsd o b p p 3 plex, Ϫ2 Ϫ1 k (60ЊC) ϭ (1.50 Ϯ 0.03) ϫ 10 s ; ⌬H ‡ ϭ 61 Ϯ