Chromium(II) and Chromium(III) Complexes Supported by Tris(2-pyridylmethyl)amine: Synthesis, Structures, and Reactivity
β Scribed by Robertson, Nicholas J.; Carney, Michael J.; Halfen, Jason A.
- Book ID
- 120395755
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 183 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
## Abstract Tris(2β²β[2βphenylβ1,3βdioxolano])chromium(III) **3** has been synthesised and has been shown to have the __cis__ (or __fac__) configuration **3a** by Xβray analysis: the Crο£ΏC bond length is 2.037 (10) Γ .
Heterotrinuclear CrlU-pdn-Cr In complexes of formulae [Cr(salen)-Pd(dmg)z-Cr(salen)]'H20 (1), [Cr(salen)-Pd(~-BD)2-Cr(salen)]-H20 (2) and [Cr(salen)-Pd(~-FD)z-Cr(salen)]-2H20 (3) [dmg2-=dimethylglyoximato, (~-BD)~-= ~-benzyldioximato, (~-FD)~-= :~-furildioximato and salen 2 -= N,N'-ethylenebis(sali