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Chromic acid oxidation of oxalic acid — II: Kinetic investigation of the manganese(II) catalysed oxidation of oxalic acid by chromium(VI)

✍ Scribed by G.V. Bakore; C.L. Jain


Book ID
118907652
Publisher
Elsevier Science
Year
1969
Weight
234 KB
Volume
31
Category
Article
ISSN
0022-1902

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The oxalic acid catalysed oxidation ofbi
✍ Tatakuntla Satyanarayana; Nageswara Rao Anipindi; Veeraputhiran Subbiah; Madhusu 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 284 KB

The reaction between bis (2,4,6-tripyridyl-l,3,5-triazine)iron(II), Fe(TPTZ)~ + and chromium(VI) in acetate buffers is very slow. However, in the presence of oxalic acid (catalyst) it is very fast and is completed within 10 s. The reaction was studied in the 3.6-5.6 pH range using stoppedflow spectr