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Chromatography of N-methylcarbamates in the gaseous phase

✍ Scribed by Larry Wheeler; Allen Strother

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
710 KB
Volume
45
Category
Article
ISSN
1873-3778

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✦ Synopsis

Gas-liquid chromatography was used to successfully separate certain pesticidal phenyl N-mcthylcarbamates from their phenolic moieties. A slightly polar 3 y,& OV-17 liquid phase was utilized and compared with a mixed liquid phase polarity column, 1.5 o/0 SE-30 and 2 o/o Carbowas zoM. Retention times, carbamate to phenol ratios, peak symmetry values and height equivalent to a theoretical plate values are reported as functions dependent on temperature. Small amounts of breakdown products were observed with a majority of tile compounds at rSo" on the OV-17 column.

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