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Chromatographic micro method for determining amino acid configurations

✍ Scribed by Theodor Wieland; Angeliki Buku


Book ID
107710952
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
117 KB
Volume
27
Category
Article
ISSN
0003-2697

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## Abstract Enantiopure α‐amino acids were converted to 4‐substituted 2‐aryl‐ and 2‐alkyl‐5(4__H__)‐oxazolones under partial racemization. These nonracemic mixtures were dissolved in CDCl~3~, an equimolar amount of the chiral dirhodium complex $Rh^{\rm (II)}\_{2}$[(__R__)βˆ’ (+)βˆ’ MTPA]~4~ (MTPA‐H = M