Chromatographic evidence for the existence of a manganese porphyrin in erythrocytes
β Scribed by R.G.V. Hancock; K. Fritze
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 682 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0006-3061
No coin nor oath required. For personal study only.
β¦ Synopsis
Erythrocyte hemolysate, prepared from blood withdrawn six days after the injection of %inClz into a rat, contained a significant amount of S*Mn. The gel chromatographic behavior of the S*Mn-containiig compounds wss identical to that of hemoglobin, bispyridinehemochrome, and hematin. However, no association of S*Mn and these iron-containing species wss observed in vitro. This evidence indicates the in v&o formation of a manganese porphyrin.
π SIMILAR VOLUMES
Evidence is reported herein that heating 6-carbanethoxy-1,2,3-benzothiadiazole, 1, yields nitrogen and 3-carbomethoxybenzothiirene, 2, which subsequently forms 2,7-and 2,8-dicarbomethoxythianthrene, 3, and 4, respectively (Equation 1).