Cholesteric Liquid-Crystalline Side-on Polysiloxanes: Effects of Biaxiality on the Cholesteric Structure

✍ Scribed by Hiroshi Ogawa; Elke Stibal-Fischer; Heino Finkelmann

• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 242 KB
• Volume: 205
• Category: Article
• ISSN: 1022-1352
• DOI: 10.1002/macp.200300231

✦ Synopsis

Abstract

Summary: Biaxial side‐on cholesteric copolysiloxanes with laterally attached mesogenic groups were investigated in mixtures with a low molar mass liquid crystal. While mixtures with a low concentration of the polymer exhibit the conventional fingerprint texture, for concentrations above about 60 mol‐% characteristic irregularities appear in the cholesteric structure that are obviously due to phase biaxiality. Besides the absence of pseudo‐isotropic lines, irregular patterns perpendicular to the helix axis emerge and the periodic distance of regions with similar optical properties along the helix axis is strongly disturbed. This suggests that the photonic band gap width of a uniaxial cholesteric phase becomes strongly affected when a phase transformation into a biaxial cholesteric phase occurs.

Cholesteric fingerprint texture of a mixture of uniaxial nematic monomer and biaxial cholesteric polymer.

magnified imageCholesteric fingerprint texture of a mixture of uniaxial nematic monomer and biaxial cholesteric polymer.