Epoxidations of a-cyclogeranyl systems, such as 1 [Eq. ( )], occur syn to the alkyl group at C3, contrary to expectation based upon steric effects. To determine the origin and scope of this effect, transition structures have been located for oxygen transfer from peracetic acid to several substitute
✦ LIBER ✦
CH⋅⋅⋅O Hydrogen Bonding Influences π-Facial Stereoselective Epoxidations
✍ Scribed by Ilyas Washington; K. N. Houk
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 134 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
CH⋅⋅⋅O Hydrogen Bonding Influences π-Fac
✍
Ilyas Washington; K. N. Houk
📂
Article
📅
2001
🏛
John Wiley and Sons
🌐
English
⚖ 130 KB
ChemInform Abstract: Diastereoselective
✍
Waldemar Adam; Simon B. Schambony
📂
Article
📅
2001
🏛
John Wiley and Sons
⚖ 35 KB
👁 1 views
Ab initio study of the effect of CH ···
✍
D. Suárez; R. López; J. González; T. L. Sordo; J. A. Sordo
📂
Article
📅
1996
🏛
John Wiley and Sons
🌐
English
⚖ 402 KB
👁 3 views
Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en