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C−H···O Bonded Dimers in Liquid 4-Methoxybenzaldehyde: A Study by NMR, Vibrational Spectroscopy, and ab Initio Calculations

✍ Scribed by Karger, N.; Amorim da Costa, A. M.; Ribeiro-Claro, Paulo J. A.


Book ID
127281766
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
78 KB
Volume
103
Category
Article
ISSN
1089-5639

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Evidence of dimerization through C—H···O
✍ Paulo J. A. Ribeiro-Claro; L. A. E. Batista de Carvalho; Ana M. Amado 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 355 KB 👁 1 views

The vibrational spectra of 4-methoxybenzaldehyde in the liquid phase show pairs of bands whose temperature-and solvent-dependent behaviour can hardly be interpreted only in terms of a cis-trans conformational equilibrium. In particular, the solvent and temperature-dependent intensities of the mCxO b