Chloroperoxidase-catalyzed asymmetric oxidations: substrate specificity and mechanistic study.
β Scribed by Zaks, Aleksey; Dodds, David R.
- Book ID
- 125533275
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 686 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxoβshunt reactions under different experimental conditions wit
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