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Chloroalkylation of aryl aldehydes using alkylboron dichlorides in the presence of oxygen

✍ Scribed by George W Kabalka; Zhongzhi Wu; Yuhong Ju

Book ID
104231328
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
63 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reactions of aryl aldehydes with alkylboron dichlorides in the presence of oxygen at room temperature produces arylalkyl chlorides in good to excellent yields.

πŸ“œ SIMILAR VOLUMES

Epoxidation of methyl oleate with molecu
Epoxidation of methyl oleate with molecular oxygen in the presence of aldehydes
✍ Angela KΓΆckritz; Michael Blumenstein; Andreas Martin πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 248 KB

## Abstract The epoxidation of methyl oleate with molecular oxygen in the presence of aldehydes was investigated and optimized. Epoxide yields up to 99% were observed in organic solvents. The preponderant radical reaction was started by a single organic radical chain initiator, without using a meta