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Chloroacetylenes as Michael acceptors. II. Direct ethynylation and vinylation of tertiary enolates.

✍ Scribed by Andrew S. Kende; Pawel Fludzinski


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
241 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reaction of CICGCCI, PhC:CCI and PhSC'ICCI with a variety of tertiary enolates leads in 43-90% yields to crchloroethynyl, cl-phenylethynyl and o-thiophenylethynyl derivatives.