Truly chlorine-resistant polyamide reverse osmosis composite membranes were prepared by cross-linking the interface of the composite membrane. Such membranes possessed chlorine resistance one order of magnitude more than those of the commercially used polyamide composite membranes. The effect of the
Chlorine resistant polysulfone reverse osmosis modules
โ Scribed by A.E. Allegrezza Jr.; B.S. Parekh; P.L. Parise; E.J. Swiniarski; J.L. White
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 904 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0011-9164
No coin nor oath required. For personal study only.
โฆ Synopsis
Spiral wound reverse osmosis modules incorporating a highly chlorine resistant membrane have been developed for use in the purification of water.
The modules exhibit >95% salt rejection with product flux rates of up to 55 gal/ft2/day (gfd), at 4OOpsi transmembrane pressure, 25oC, and with softened feed water.
The modules can be operated with high chlorine concentrations, i.e., continuous exposure to 5ppm free chlorine or intermittent exposure up to 100ppm free chlorine (pH range of 5.5-10).
The modules have a pH operation range of 4-11, with excursions outside of this range allowable during cleaning procedures. Module field tests have shown good fouling resistance combined with excellent response to cleaning protocols.
๐ SIMILAR VOLUMES
Currently available polyamide (PA) reverse osmosis membranes are highly effective in their intended applications for desalination and industrial process water. However, they offer poor resistance to strong oxidants such as chlorine, resulting in chain deformation and depolymerization of the polymer.
New asymmetric hollow fiber reverse osmosis (RO) membrane was developed from a new chlorine-resistant copolyamide [4T-PIP(30)] with a piperazine moiety by a conventional phase-separation method. The new 4T-PIP(30) hollow fiber membrane has the same low-pressure RO performance as cellulose triacetate
Copolyamides were prepared from mixed diamine components of 3,3ะ-or 4,4ะ-diaminodiphenylsulfone, piperazine, and dichlorides such as isophthaloyl or terephthaloyl. The obtained copolyamides are random copolymers, which have good solubilities in organic solvents and good mechanical properties, even i