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Chlorine-oxygen interactions and the role of chlorine in ethylene oxidation over Ag(111)

โœ Scribed by S.A. Tan; R.B. Grant; R.M. Lambert

Book ID
113178008
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
751 KB
Volume
100
Category
Article
ISSN
0021-9517

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Chlorine-oxygen interactions and the rol
Chlorine-oxygen interactions and the role of chlorine in ethylene oxidation over Ag(111)
โœ S.A. Tan; R.B. Grant; R.M. Lambert ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 751 KB

Coadsorbed chlorine enhances the surface + bulk transport of chemisorbed oxygen on Ag(ll1). Preadsorbed chlorine progressively blocks the chemisorption of atomic oxygen (O(a)); O(a) uptake is completely suppressed at 0 Cl = 0.25. Reactor studies of ethylene oxidation in the presence of adsorbed chlo