Chlorination Chemistry. 1. Rate Coefficients, Reaction Mechanisms, and Spectra of the Chlorine and Bromine Adducts of Propargyl Halides
โ Scribed by Atkinson, Dean B.; Hudgens, Jeffrey W.
- Book ID
- 126436894
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 129 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
Rate coefficients have been measured for the reactions of Cl atoms with methanol (k 1 ) and acetaldehyde (k 2 ) using both absolute (laser photolysis with resonance fluorescence) and relative rate methods at 295 ฯฎ 2 K. The measured rate coefficients were (units of 10 ฯช11 cm 3 molecule ฯช1 s ฯช1 ): abs
## Abstract The rate coefficient for the gasโphase reaction of chlorine atoms with acetone was determined as a function of temperature (273โ363 K) and pressure (0.002โ700 Torr) using complementary absolute and relative rate methods. Absolute rate measurements were performed at the lowโpressure regi