Chloridotetrakis(imidazole)copper(II) chloride

✍ Scribed by Li, Ting Bin ;Hu, Ya Li ;Li, Ji Kun ;He, Guo Fang

• Book ID: 104491725
• Publisher: International Union of Crystallography
• Year: 2007
• Tongue: English
• Weight: 696 KB
• Volume: 63
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536807044108

✦ Synopsis

The title compound, [CuCl(C 3 H 3 N 2 ) 4 ]Cl, exhibits a squarepyramidal coordination of Cu II by four N atoms of four imidazole ligands and one chlorine atom located at the apex of the pyramid.

Related literature

For related literature, see Li et al. (2004).

Experimental

Crystal data [CuCl(C 3 H 3 N 2 ) 4 ]Cl M r = 402.74 Monoclinic, P2 1 =n a = 8.8662 (3) A b = 13.3199 (4) A c = 13.9190 (4) A ˚ = 90.0420 (10) V = 1643.79 (9) A ˚3 Z = 4 Mo K radiation = 1.66 mm À1 T = 293 (2) K 0.15 Â 0.12 Â 0.10 mm Data collection Bruker AXS CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T min = 0.788, T max = 0.851 18750 measured reflections 2885 independent reflections 2735 reflections with I > 2(I) R int = 0.028 Refinement R[F 2 > 2(F 2 )] = 0.025 wR(F 2 ) = 0.072 S = 1.00 2885 reflections 209 parameters