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Chloridobis(1,10-phenanthroline-κ2N,N′)copper(I) hexa­hydrate

✍ Scribed by Zhong, H. ;Zeng, X.-R. ;Yang, X.-M. ;Luo, Q.-Y. ;Xiao, S.-Z.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
912 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Cu^I^ atom in the title complex, [CuCl(C~12~H~8~N~2~)~2~]·6H~2~O, exists in a distorted trigonal-bipyramidal coordination geometry defined by one Cl atom and four N atoms of two 1,10-phenanthroline ligands. In the crystal structure, molecules are linked into a three-dimensional framework by O—H...O hydrogen bonds and π–π stacking interactions. Four water molecules lie on crystallographic twofold rotation axes.

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