The reaction between graphite fluoride and ferric chloride was observed in the temperature range of 300 to 400ยฐC. The graphite fluorides used for this reaction have an sp3 electronic structure and are electrical insulators. They can be made by fluorinating either carbon fibers or powder having vari
Chloride-fluoride-graphite ternary compounds: Preparation and characterization
โ Scribed by A Hamwi; A Senhaji; D Djurado; J Dupuis
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 641 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0008-6223
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The graphite intercalation compound (GIG) of titanium fluoride has been prepared in a fluorine atmosphere. The GICs prepared from natural graphite and pitch-based carbon fiber were mostly stage-2 compounds with repeat distance 11.28-11.59 A and composition Cll\_15TiF4.1\_6 >. The ESCA spectrum indic
The electrochemical behaviour of different graphites in molten lithium chloroaluminate electrolyte was studied using the potentiodynamic method. The oxidation currents observed at potentials below chlorine evolution are related to the oxidation of graphite during aluminium chloride intercalation.
A graphite intercalation compound of C,F(MgF& was prepared under a fluorine atmosphere of 1 atm at temperatures of 20-350ยฐC. The 1st stage compound has the identity period of 9.3-9.4& ESCA and @F NMR spectra indicate that the chemical interaction of intercalated fluorine with carbon is similar to th
Natural graphite flakes were intercalated by St+&. SbCI,F and SbC&F, at T I 125ยฐC for a reaction time of I 5 2 hours. The "'Sb Moessbauer spectra of the stage 2 intercalation compounds show only one intense line in the Sb( + 5) region. The spectra can be fitted both in terms of two inequivalent Sb(