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Chloride-bridged oxovanadium(v) complexes with alkoxyalkoxide ligands. Synthesis, structure, electrochemistry and reactivities

✍ Scribed by Rosenthal, Esther C. E.; Cui, Huiling; Koch, Juliane; Escarpa Gaede, Petra; Hummert, Markus; Dechert, Sebastian

Book ID
124080351
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
277 KB
Volume
18
Category
Article
ISSN
1477-9226

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The aminoalcohol ligands diethanolamine (H 2 dea) and triethanolamine (H 3 tea) react with [VO(acac) 2 ] to yield the tetranuclear oxovanadium(IV) complexes [{VO(dea)} 2 -{VO(acac)} 2 (Β΅ 2 -OMe) 2 ] (1) and [{VO(Htea)} 2 {VO(acac)} 2 (Β΅ 2 -OMe) 2 ] (2). In the case of the potentially bridging aminoa