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Chlorid-induzierte Umwandlung von [Mn4O2(OAc)6(py)2(dbm)2] in [Mn4O3Cl(OAc)3(dbm)3]: Mögliche Bedeutung für die photosynthetische Wasseroxidation

✍ Scribed by Sheyi Wang; Dr. Kirsten Folting; Dr. Wiliam E. Streib; Edward A. Schmitt; James K. McCusker; Prof. Dr. David N. Hendrickson; Prof. Dr. George Christou


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
365 KB
Volume
103
Category
Article
ISSN
0044-8249

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Chloride-Induced Conversion of [Mn4O2(OA
✍ Sheyi Wang; Dr. Kirsten Folting; Dr. William E. Streib; Edward A. Schmitt; James 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 265 KB

We are currently seeking models for the various oxidation levels (S, states; n = -1 through 4) of the photosynthetic water oxidation center (WOC), to assist in the elucidation of its nature and mode of action.1'l The WOC requires four Mn atoms for activity, and these are 0x0-bridged and ligated by 0