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Chiroptical studies on 5-thio-, 1,5-dithio-D-glycopyranosides and extension of ring oxygen helicity rule to ring sulphur

✍ Scribed by Hiroshi Meguro; Emiri Ohtaki; Katura Tuzimura; N.A. Hughes; Leslie Hough

Book ID: 108384640
Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 210 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85644-6

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Chiroptical studies on 1-thio-D-glycopyr

Chiroptical studies on 1-thio-D-glycopyranosides and a proposal of ring oxygen helicity rule

✍ Emiri Ohtaki; Hiroshi Meguro; Katura Tuzimura 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 228 KB

Previously') we reported ORD and CD of some I-thio-\_pglycofuranosides as model compounds of D\_glycofuranosides. There it was revealed that the second band of the ring oxygen (140-170 nm) should be the most important in determining anomeric configurations and that the rotational strengths of the ba