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Chiroptical Spectra of 1,2-Cyclopropanedicarboxylic Monothioimides 1

✍ Scribed by Gdaniec, Maria; Połoński, Tadeusz


Book ID
127022668
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
121 KB
Volume
62
Category
Article
ISSN
0022-3263

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Stereochemistry and chiroptical spectra
✍ Maria J. Milewska; Maria Gdaniec; Tadeusz Poloński 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 381 KB

Several optically active substituted 3-azabicyclo[3.1.0]hexan-2-ones and their thiocarbonyl analogues have been synthesized, and their circular dichroism spectra studied. The crystal structure of thiolactam la showed that the bicyclic skeleton of the title compounds assumes a sofa-like geometry. It