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Chiroptical Properties of the Ketene and Diazo Chromophores. 1. Conformation and Optical Activity of 1-Alken-1-ones and 1-Diazoalkanes vs Aldehydes

✍ Scribed by Shustov, Gennady V.; Sun, Fang; Sorensen, Ted S.; Rauk, Arvi


Book ID
125893048
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
252 KB
Volume
63
Category
Article
ISSN
0022-3263

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Enantiopure Dendrimers Derived from the
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of the DeVoe polarizability model the intensity of the 1 B couplet has been calculated vs. the dihedral angle ΞΈ. This The absorption and CD spectra of a series of Fre Β΄chet (compounds 7-10) and backfolding (compounds 11-12) analysis provides ΞΈ angles of 95-110Β°for the Fre Β΄chet dendrimers and 100-11