𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chiroptical properties of S-alkyl derivatives of 1-thioglycerol

✍ Scribed by Peter Michelsen; Bengt Herslöf; Björn Åkesson

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
550 KB
Volume
29
Category
Article
ISSN
0009-3084

No coin nor oath required. For personal study only.

✦ Synopsis

Several racemic and optically active S-alkyl derivatives of l-thioglycerol have been synthesized. From 3-S-tetradecyl-3-thio-sn-glycerol the dioleoyl and diacetyl esters were prepared. 1,2-Dioleoyl-3-S-tetradecyl-3-thio-sn-glycerol was converted into the corresponding sulphoxide and sulphone. The ehiroptical properties of these compounds were investigated by ORD and CD. Such measurements can be used in studies on the metabolism of enantiomeric acyiglycerols.

📜 SIMILAR VOLUMES

Chiroptical properties of S-proline conf
Chiroptical properties of S-proline conformational isomers
✍ F. S. Richardson; S. Ferber 📂 Article 📅 1977 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 798 KB

## Abstract The chiroptical properties of S‐proline conformational isomers are examined on a theoretical model in which electronic wave functions are obtained from semiempirical molecular orbital calculations. The CNDO/S molecular orbital model is used to perform SCF‐MO calculations on ground state