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Chiroptical properties of chiral olefins

โœ Scribed by Gedanken, Aharon.; Duraisamy, M.; Huang, Jiling.; Rachon, J.; Walborsky, Harry M.


Book ID
124097379
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
974 KB
Volume
110
Category
Article
ISSN
0002-7863

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Ion-pairs of 2-benzoylbenzoic acid-chiral amine display a large induced circular dichroism ( ICD ) on the n -h" transition of the carbonyl group under lower concentration of the salt than 10s2 mole/l in non-polar solvents such as 1 carbon tetrachloride and benzene. The origin of the large ICD effec