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Chiroptical properties of C2-symmetric N-haloaziridines. Chiral rules for the N-haloaziridine chromophore

✍ Scribed by Shustov, G. V.; Kachanov, A. V.; Korneev, V. A.; Kostyanovsky, R. G.; Rauk, A.


Book ID
120371832
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
787 KB
Volume
115
Category
Article
ISSN
0002-7863

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By use of an asymmetric Ullmann coupling involving chiral naphthalene oxazolines 1, the title compounds were prepared in good yields and with high diastereoselectivity. Hydrolysis of the binaphthyl oxazolines 2 led to the di-aldehydes 5, which were transformed into the azepine derivative, 6. The lat