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Chirality Induction in Cyclopolymerization. 3. Template Effect of Chiral Acyclic 1,3-Glycols on the Cyclocopolymerizations of ( S )-1,3-Butanediyl and (2 S ,4 S )-2,4-Pentanediyl Bis(4-vinylbenzoate)s with Styrene

✍ Scribed by Kakuchi, Toyoji; Haba, Osamu; Uesaka, Takahiro; Obata, Makoto; Morimoto, Yasushi; Yokota, Kazuaki


Book ID
126406339
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
219 KB
Volume
29
Category
Article
ISSN
0024-9297

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Chirality induction in cyclopolymerizati
✍ Toyoji Kakuchi; Osamu Haba; Takahiro Uesaka; Yukio Yamauchi; Makoto Obata; Yasus πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 561 KB

## Abstract The copolymerizations of (__S__)‐1,2‐propanediyl and (2__S__,3__S__)‐2,3‐butanediyl bis(4‐vinyl‐benzoate)s (2a and 2b) (M~1~) with styrene (M~2~) were carried out using 2,2′‐azoisobutyronitrile in toluene at 60 Β°C. For the cyclocopolymer 3, the extent of cyclization of 3b is higher than