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Chiral(arene)tricarbonylchromium complexes: resolution of aldehydes

✍ Scribed by Solladie-Cavallo, Arlette; Solladie, Guy; Tsamo, Etienne


Book ID
121272840
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
446 KB
Volume
44
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Planar chiral arene tricarbonylchromium
✍ E.Peter KΓΌndig; Anna Quattropani πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 345 KB

Sequential reaction of pmchiral (r$arene)Cr(CO)~ complexes with chiral amide bases and electrophiles yielded planar chiml complexes. Benzaldehyde acetal and phenyl carbamate complexes gave o-substituted products with 64 to 81% enautiomeric excess. With the bemaldehyde acetal complex. competitive ben