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Chiral symmetric crowns incorporating the 4,6-O-benzylidene derivatives of methyl α-D-glucopyranoside and methyl α-D-galactopyranoside. A configurational impediment to complexation of organic cations by 18-crown-6 derivatives

✍ Scribed by Dale A. Laidler; J.Fraser Stoddart; John B. Wolstenholme

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
275 KB
Volume
20
Category
Article
ISSN
0040-4039

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Complexation selectivity by chiral asymm
Complexation selectivity by chiral asymmetric crowns incorporating the 4,6-O-benzylidene derivatives of methyl β-D-glucopyranoside and methyl β-D-galactopyranoside. A secondary anomeric effect?
✍ Roger B. Pettman; J.Fraser Stoddart 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 289 KB

S3 7t!F Chiral asymmetric crowns have been derived from the 4,6-0-benzylidene derivatives of methyl a-p-gluco-, 2a-c a-Q-galacto-, 2a-c and a-P-manno-2c'd pyranosides. The temperature dep-