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Chiral Selenium Compounds: Versatile Reagents in Organic Synthesis

โœ Scribed by Wirth, Thomas

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
783 KB
Volume
1997
Category
Article
ISSN
0947-3440

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โœฆ Synopsis

synthesis I Diselenides / Natural products / Selenium I Total synthesis Chiral diselenides are easily accessible and can be used for various asymmetric reactions. Oxy-and aminoselenenylations with selenium electrophiles generated from the diselenides are used to build new asymmetric centers in the addition products. Improvements in the synthesis of chiral diselenides are described as well as the generation of addition prod-ucts suitable for natural product synthesis. Oxyselenenylation-elimination sequences can be performed with catalytic amounts of chiral diselenides. In addition, such compounds can be used as ligands in other metal-catalyzed asymmetric reactions.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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