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Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions

✍ Scribed by Michael P. Doyle; Bridget D. Brandes; Amy P. Kazala; Roland J. Pieters; Michael B. Jarstfer; Linette M. Watkins; Cassandra T. Eagle

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 270 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)97128-4

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✦ Synopsis

Chiral Fth& (L = 4-substituted-oxazolidinones and methyl 2-pyrrolidone+carboxyIate) having two nitrogen-rhodfum bonds in the cis geometry at each rhodium face are effective catalysts for enantioselective intermolecular cyclopropanation reactions.

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