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Chiral Recognition of Dicarboxylate Anions by Sapphyrin-Based Receptors

✍ Scribed by Sessler, Jonathan L.; Andrievsky, Andrei; Král, Vladimír; Lynch, Vincent

Book ID
127165774
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
234 KB
Volume
119
Category
Article
ISSN
0002-7863

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Anion recognition properties of D-ribose-based receptors aand b-1 were measured by 1 H NMR in CDCl 3 and MeCN-d 3 . Receptor b-1 showed effective binding with anions by cooperative hydrogen bonds of cisdiol. The anomeric isomer a-1 is a less effective anion receptor which has similar cis-diol as a r