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๐Ÿ“

Chiral Reactions in Heterogeneous Catalysis

โœ Scribed by Georges Jannes, Vincent Dubois (auth.), Georges Jannes, Vincent Dubois (eds.)


Publisher
Springer US
Year
1995
Tongue
English
Leaves
204
Edition
1
Category
Library

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โœฆ Synopsis


It was a great honor for us to organize ChiCat, a symposium devoted to Chiral Reactions in Heterogeneous Catalysis and to be the hostsofmore than 120 scientists coming from everywhere in the industrialized world, to celebrate together one century of existence ofInstitut Meurice. This school was established in 1892when an industrial chemist, named Albert Meurice, decided to educate practical chemists according to the perceived needs ofthe industry ofthat time. This is exactly what we are still trying to do. It is the reason why, thirty years ago, we started a research activity in catalysis, and why we progressively devote this research to the applications of catalysis in the field of fine chemicals. In this respect, we are very close to another initiative of Albert Meurice, who started the first production of synthetic pharmaceuticals in Belgium during World War I. This business later on became a part ofthe Belgian corporation DCB, still very active in pharmaceuticals today. The school created by Albert Meurice merged in the fifties with another school that had been created to meet the same needs in the field of the food industries, mainly distilleries and breweries. This merger was done in the frame of the establishment of CERIA. For people in catalysis, ceria stands for cerium oxide, but for those who engineered the concept, CERIA stood for Center of Education and Research for the Food and Chemical Industries.

โœฆ Table of Contents


Front Matter....Pages i-xv
Introduction....Pages 1-2
Front Matter....Pages 3-3
Commercial Outlook for Chirality. Quo Vadis ?....Pages 5-19
Strategies For Asymmetric Synthesis. What Is The Role Of Heterogeneous Catalysis?....Pages 21-28
Homogeneous Enantioselective Catalysis....Pages 29-32
Scope and Limitations of the Application of Heterogeneous Enantioselective Catalysts....Pages 33-57
Front Matter....Pages 59-59
Modification of Supported and Unsupported Nickel Catalysts by ฮฑ-Amino and ฮฑ-Hydroxy Acids for Chiral Reactions....Pages 61-74
Enantio-Differentiating Hydrogenation Of Simple Alkanones With Asymmetrically Modified Heterogeneous Catalyst....Pages 75-81
Enantio-Differentiating Hydrogenation of 2-Butanone : Distinction Between CH 3 and C 2 H 5 With A Modified Nickel Catalyst....Pages 83-88
Chiral Hydrogenation of Estrone and Estrone-3-Methyl Ether....Pages 89-93
Enantioselective Hydrogenation of ฮฑ-Ketoesters: A Molecular View on the Enantio-Differentiation....Pages 95-103
Studies of the Platinum Cinchona Alkaloid Catalyst for Enantioselective ฮฑ-Ketoester Hydrogenation....Pages 105-110
Asymmetric Hydrogenation of Ethyl Pyruvate Using Ptcontaining Zeolites Modified With (-)-Cinchonidine....Pages 111-118
Front Matter....Pages 119-119
Heterogeneous Catalytic Reactions Using Chiral Auxiliaries and Producing Enantiomers in Excess....Pages 121-133
Enzymatic Resolution of Biologically Active Precursors Versus Asymmetric Induction in Heterogeneous Catalysis....Pages 135-139
Enantio- and Diastereoselective Reduction of Disubstituted Aromatics....Pages 141-145
Heterogeneous Asymmetric Catalysis with C 2 Symmetric Amine-Modified Rhodium/Silica....Pages 147-149
An Investigation of the Mode of Hydrogen Addition in Stereoselective Heterogeneous Catalytic Hydrogenations....Pages 151-153
Heterogeneous Enantioselective Hydrogenation and Dihydroxylation of Carbon Carbon Double Bond Mediated by Transition Metal Asymmetric Catalysts....Pages 155-176
Front Matter....Pages 177-177
Chiral Dioxo-Molybdenum Complexes Anchored to Modified Usy-Zeolites. Application to Selective Epoxidation of Olefins....Pages 179-189
Effect of Sulfoxide Loading on the Selectivity and Activity of Zeolite Y for Dehydration Reactions....Pages 191-195
Front Matter....Pages 177-177
Novel Chiral Ruthenium-Bis(Oxazolinyl)Pyridine and Bis-(Oxazolinyl)-Bipyridine Complexes: Asymmetric Cyclopropanation of Styrene with Diazoacetates....Pages 197-201
Polymer Supported N- Alkylnorephedrines as Highly Enantioselective Chiral Catalysts for The Addition of Dialkylzincs to Aldehydes....Pages 203-207
Back Matter....Pages 209-212

โœฆ Subjects


Catalysis; Medicinal Chemistry; Physical Chemistry; Pharmacy; Characterization and Evaluation of Materials


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