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Chiral P,N-Ligands with Pyridine-Nitrogen and Phosphorus Donor Atoms. Syntheses and Applications in Asymmetric Catalysis

โœ Scribed by Giorgio Chelucci; Gianmauro Orru; Gerard A. Pinna


Book ID
101951949
Publisher
John Wiley and Sons
Year
2004
Weight
51 KB
Volume
35
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


๐Ÿ“œ SIMILAR VOLUMES


A Pโˆ—-chiral bisdiamidophosphite ligand w
โœ Konstantin N. Gavrilov; Sergey V. Zheglov; Pavel A. Vologzhanin; Marina G. Maksi ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 117 KB

A novel readily available P,P-bidentate diamidophosphite ligand with P \* -stereocentres is prepared from an inexpensive C 2 -symmetric 1,4:3,6-dianhydro-D-mannite. By using this efficient ligand, up to 98% ee is achieved in Pd-catalysed asymmetric allylic alkylation, up to 92% ee in Pd-catalysed as