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Chiral Phosphine-Catalyzed Enantioselective Construction of γ-Butenolides Through Substitution of Morita−Baylis−Hillman Acetates with 2-Trimethylsilyloxy Furan

✍ Scribed by Jiang, Ying-Qing; Shi, Yong-Ling; Shi, Min

Book ID
120240238
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
236 KB
Volume
130
Category
Article
ISSN
0002-7863

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✍ Ying-Qing Jiang; Yong-Ling Shi; Min Shi 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

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Diastereo- and Enantioselective Construc
Diastereo- and Enantioselective Construction of γ-Butenolides through Chiral Phosphane-Catalyzed Allylic Alkylation of Morita–Baylis–Hillman Acetates
✍ Yin Wei; Guang-Ning Ma; Min Shi 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 731 KB

## Abstract A series of multifunctional, chiral amide–phosphane organocatalysts have been designed and synthesized for the allylic substitution of Morita–Baylis–Hillman (MBH) acetate with 2‐trimethylsilyloxyfuran for butenolide synthesis. This reaction was achieved in good to excellent yield (42–98