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Chiral Palladium(II)−Bis(trichlorosilyl) Complexes. Synthesis, Structure, and Combined QM/MM Computational Studies

✍ Scribed by Woo, Tom K.; Pioda, Giorgio; Rothlisberger, Ursula; Togni, Antonio


Book ID
127230706
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
162 KB
Volume
19
Category
Article
ISSN
0276-7333

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Novel cationic allylpalladium(II) complexes containing the alkaloid (-)-sparteine (1) as a bidentate ligand have been prepared. Two of them, [q3-(cyclohex-2-enyl)] (sparteine)palladium(II) hexafluorophosphate ([Pd(v3-C6H,)(sparteine)][PF6]; 3b) and (sparteine)[~3-(1,1,3-triphenylallyl)]palladium(II)