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Chiral N-Heterocyclic Carbene Ligands Derived from 2,2‘-Bipiperidine and Partially Reduced Biisoquinoline: Rhodium and Iridium Complexes in Asymmetric Catalysis †

✍ Scribed by Herrmann, Wolfgang A.; Baskakov, Denys; Herdtweck, Eberhardt; Hoffmann, Stephan D.; Bunlaksananusorn, Tanasri; Rampf, Florian; Rodefeld, Lars


Book ID
127108297
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
161 KB
Volume
25
Category
Article
ISSN
0276-7333

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Palladium complexes with abnormal N-hete
✍ Thandavamurthy Karthikeyan; Sethuraman Sankararaman 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 524 KB

Chiral and achiral pincer type palladium complexes bearing abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazole are reported. Both complexes are effective as catalysts for non-asymmetric Suzuki coupling reaction for the synthesis of biphenyl derivatives. However, both the complexes fa