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Chiral metal complexes as probes in electron-transfer reactions involving metalloproteins

✍ Scribed by Klaus Bernauer; Simona Ghizdavu; Luca Verardo

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 132 KB
Volume: 190-192
Category: Article
ISSN: 0010-8545
DOI: 10.1016/s0010-8545(99)00094-6

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## Abstract The mechanism of oxidation of ternary complexes, [Co^II^(nta)(S)(H~2~O)~2~]^3−^ and [Co^II^(nta)(M)(H~2~O)]^3−^ (nta = nitrilotriacetate acid, S = succinate dianion, and M = malonate dianion), by periodate in aqueous medium has been studied spectrophotometrically over the (20.0–40.0) ±